Wollastonite
a met silicate of calcium having the formula CaSiO2
and usually occurs as aggregated of bladed or needle like
crystals. It is generally white in color, has a specific
gravity of 2.8 to 3 hardness of 4.5 to 5 and melting point
of about 1540° C.
Excellent
dielectric properties, high resistance to heat chemical
inertness and brilliant whiteness in powdered state are
some of the qualities for which it is valued in various
industries. Wollastonite is largely used in ceramic industry
for making electrical insulations and glazed tiles. It is
also used as an extender in paints, as paper coating, filler
in plastics and rubber goods, fluxing material for welding
rods.
There
is no BIS specification for this mineral. However, the user
industry prescribed their own specifications, which are
enumerated below:
|
S.
No. |
Industry |
Specifications |
|
1. |
Asbestos
product |
Wollastonite
powder, 300 mesh size with CaSiO2
75
to 80%
|
|
2. |
Ceramic |
Wollastonite
powder having expansion on firing,
size
250 mesh CaO – 46-48%, SiO2 51=52%
|
|
3. |
Electrode |
Wollastonite
powder size – 250 mesh, CaO :
46-48%,
SiO2 : 50%
|
Wollastonite
Pct. Ltd., are the only producer of this mineral. They supply
this mineral from their mines in Rajasthan of the following
specifications various industries.
|
CaO |
48.02% |
TiO2 |
In
trace |
|
SiO2 |
48.77% |
MnO |
0.29% |
|
MgO |
0.06% |
Na2O |
0.02% |
|
Al2O3 |
0.66% |
K2O |
0.11% |
|
Fe2O3 |
0.43% |
L.
O. I. |
1.68% |
The
party supplies the above grade with the following guarantees.
|
CaO
+ SiO2 |
96.5%
(min.) |
|
Al2O3 |
1.5% |
|
Fe2O3 |
0.5%
(max.) |
|
L.
O. I. |
2.0%
(max.) |
Physical
Requirements:
|
Sp.
Gravity |
2.9 |
|
Bulk
density |
855
Kg/M2 |
|
Oil
absorption |
25
– 30 lbs/100lbs |
|
pH
of 10% slurry |
9.0 |
|
Solubility
in water |
0.0095
gm/100cc. |
|
Melting
point |
1540°
C |
Future
Trends: - Wollastonite is one of the latest minerals
added to the list of industrial minerals marketed today.
Its industrial application are growing gradually, over the
past 30 years, it has become an important functional filler
in a number of products including plastics, adhesives, pesticides,
paints, and paper. This mineral was being tried as a possible
substitute for asbestos all over the world. In India CBRI,
Roorkee carried out research on substitution of asbestos
by wollastonite in asbestos cement products, but the result
so far are not very encouraging.
Only
total reserves of Wollastonite have been tabulated and no
classification according to end use could be given, as no
date on the same was available in the inventory of Wollastonite.
However, the end uses of Wollastonite have been mentioned
with the reserves.
In
India at present only one namely M/s Wolken (India) Ltd.,
are producing this mineral and supply the same to various
industries with the specifications mentioned earlier page.
The
reserves of Wollastonite may be classified as under:
Marketable
Grade:
|
Chemical: |
|
CaO
+ SiO2 |
96.5%
(min.) |
|
Fe2O3 |
0.5%
(max.) |
|
Al2O3 |
1.5%
(max.) |
|
L.
O. I. |
2.0%
(max.) |
Physical
Requirements:
Sp.
Gravity
-
3.9