Sillimanite
(Al2 SiO2) forms mullite (3Al2O3.
2SiO2), on heating and the conversion to mullite
is without any appreciable volumetric changes; the maximum
expansion by volume is 4%. Mullite is a stable product
up to a temperature of 1810° C. One outstanding feature
of sillimanite is that the volume of porosity of grains
hardly exceeds 6% after heating. It has many other valuable
properties that distinguish it as a super duty refractory
material.
Sillimanite
is used in refractory industry alone. The user industries
prescribe the following two graders for specifications:
| |
Grade-I |
|
Grade-II |
|
1. |
Al2O3
|
58%
min. (Preferably 60%) |
55%
min. |
|
2. |
SiO2 |
37%
|
-- |
|
3. |
Fe2O3
|
1.5%
max. (Preferably 1%) |
1.5
max. |
|
4. |
L.
O. I. |
6.32
to 10% |
-- |
|
5. |
TiO2 |
3% |
-- |
|
6. |
Size
PCE
|
Lumps
- 2.5 to 10cms --
36
to 38 on Orton Cone (Equivalent to 1790°C to 1810°C)
|
The
above specifications were for lumpy sillimanite.
The
sub-committee on refractory raw material of the development
panel on refractories appointed by DGTD in their report
dated August 1985 has suggested the following specifications.
| |
Constituents |
Lumps
Grade-I
Grade-II
|
Beach
Sand |
|
1. |
Al2O3 |
58
min. |
54
min. |
58
min. |
|
2. |
Fe2O3 |
1.5%
max. |
1.5%
max. |
0.75%
max. |
|
3. |
Vol.
Expansion at 1500°C for two hrs. |
3.0%
max. |
3.0%
max. |
-- |
|
4. |
P.
C. E. (Orton cone) |
37
min. |
36
min. |
37
min. |
**
IBEL, however, strive to produce sillimanite concentrate
of 60% Al2O3.
Physical
Characteristics:
a)
Lumpy Ore:
Mineral should not be below 10mm in size.
It should be free from micaceous and other impurities
such as garnet, tourmaline, etc.
b)
(i) Sand grains should be free from any coating material,
as bricks made from coated material are prone to spelling.
(ii)
Size fraction in microns may represent to the following
percentage:
|
Size
(in microns) m |
% |
|
+420 |
5
- 6 |
|
+300 |
16
- 18 |
|
+250 |
18
- 20 |
|
+180 |
36
- 38 |
|
+125 |
11
- 13 |
|
+70 |
2
- 3 |
Future
trends: Beach sands contain appreciable amount of
sillimanite grains. It is, however, known that some refractory
plants in India have been using beach sand sillimanite
produced by IRLE in the manufacture of high-alumina bricks.
The performance of these bricks vis-à-vis with those made
out of lumpy sillimanite is not known. Recent survey made
by IBM reflected that Indian refractory makers could utilize
beach sand sillimanite to the tune of 15,000 to 20,000
tpa. it regular supplier are assured.
With
the gradual depletion of massive sillimanite deposits,
the use of granular sillimanite is likely to increase
in future. Beneficiation of low-grade quartz. Sillimanite
rock may also receive attention.
The
following end-use classification of reserves has been
reported in the mineral inventory as on 01.01.1985.
|
i |
Massive
a)
High-grade
b)
Medium-grade
c)
Low-grade
|
+58 Al2O3
50
– 58% Al2O3
40
– 50% Al2O3
|
|
ii |
Granular |
Beach
sand has been classified as granular type. |
|
iii |
Quartz-sillimanite
roc |
Conditional
resource (not usable at present). |
The
following end use grades for the purpose of classification
of reserves of sillimanite are prevalent.
Refractory
Grade:
|
i.Sillimanite (Lumps)
Al2O3
Fe2O3
Volume
of expansion at 1500°C for two hrs.
PCE
|
54% min.
1.5%
max.
3% max.
36% min. (Orton)
|
|
(ii)
Sillimanite (granular)
Al2O3
Fe2O3
PCE
Physical
Granular
|
58% min.
0.75%
max.
37%
min. (Orton cone)
Lumps
not below 10mm
Free
from any coating.
|