Kyanite
is an important mineral used for the production of
super duty refractory material mullite (3Al2O3
2SiO2) used mostly in non-ferrous metallurgical
and glass industries. Kyanite has the chemical composition
Al2O3 SiO2. It is
converted in to mullite and free silica when heated
to about 1350o C. This conversion takes
place with about 20% increase in volume and hence
it is necessary to calcine kyanite before use. The
outstanding advantages of refractory bricks made from
kyanite are: - (i)
Higher modules of rupture, (ii) lower Co-efficient
of expansion, (iii) increased firing range and temperature,
(iv) increased durability (v) negligible change in
volume after prolonged heating, (vi) negligible change
in volume and (vii) very low co-efficient of spelling.
The
only industry in which kyanite is used is refractory
industry. The BIS has not standardized any specifications.
However, various specifications and terminology
have ben in use by the refractory makers and the
kyanite producers. Recently the Sub-Committee on
Refractory Raw Material appointed by the Directorate
General of Technical Development (DGTD) has recommended
the following specifications.
|
|
|
Grade
- I |
Grade
- II |
|
1. |
Al2O3 |
58%
(min.) (Preferably 60%) |
54%
(min.) |
|
2. |
Fe2O3
|
1.5%
(max.) |
1.5%
(max.) |
|
3. |
P.
C. E. (Orton) |
37
(min.) |
36
(min.) |
|
4. |
Size |
25mm
to 300mm |
-- |
There
is presently no technology for using granular kyanite
either in refractory industry or in any other industry.
Future
Trend: -
With the gradual depletion of high-grade limply
kyanite, the need to beneficiate low-grade quartz
kyanite, rock and use the concentrate, has been
felt. The Indian Bureau of Mines have successfully
beneficiated low-grade kyanite of Singhbhum district
provides by Hindustan Copper Ltd., and have already
supplied over 3 tonnes of the beneficiated product
to CCCRI to make high alumina bricks and test their
suitability there is also possibility of utilizing
beach and kyanite in the manufacture of refractory.
The
following basis has been followed for the classification
of reserves in the inventory as on 01.01.1985.
|
High-grade |
(+)
58% Al2O3 |
|
Medium-grade |
50
to 58% Al2O3 |
|
Low-grade |
40
to 50% Al2O3 |
|
Conditional
reserves |
Low-grade
quartz kyanite rock. |
After
examining the specification prescribed by the Sib-Committee
on refractory Raw Material of the DGTD, the group
recommends the following end use classification
of reserves.
|
Refractory
Grade: |
Al2O3:
54% (min.)
Fe2O3: 1.5% (max.)
P. C. E.: 36% (min.) (Orton)
Size:
25mm to 300mm |
|
Conditional:
|
Quartz
kyanite rock and beach sand kyanite. |