Asbestos
is a generic term given to a group of fibrous minerals, commercial
varieties being (a) Serpentine Group chrysotile and (b) amphibole
group – Amosite, actinolite, anthophyllite, crocidolite and
tremolite. The chemical composition of the asbestos mineral
is as follows:
| (a)
Serpentine Group |
|
|
| |
Amosite |
MgFe6
(OH Si4O11)2 |
| |
Actinolite |
Ca2
(MgFe)5 (OH Si4O11)2 |
| |
Anthophyllite |
(MgFe)7
(OH Si4O11)2 |
| |
Crocidolite |
Na2
Fe5 (OH Si4O11)2 |
| |
Tremolite |
Ca2
(MgFe)5 (OH Si4O11)2 |
Asbestos
owes its commercial utility due to combination of remarkable
and unique properties like spinnability, incombustibility,
and its resistance to heat, acids and alkalis, filtration
property, tensile strength and power to absorb cement. The
utility of asbestos is mostly dependent on its physical properties
and not so much on its chemical composition.
Chrysotile
is the most important commercial variety as it has wide industrial
applications. Amosite and crocidolite in amphibole group find
larger usage. Chrysotile, amosite and crocidolite can easily
be separated in to fibers, thermal insulating sheets, tapes,
paper, etc.
There
is no BIS standard classification of asbestos. Its industrial
use is linked with the type of asbestos. Chrysotile variety
is more fibrous than amphibole, possesses good tensile strength
and is use in the manufacture of asbestos fabrics, cement
sheets, pipes and allied products. These products are used
for brakes bands lining, insulation, fireproof clothing, etc.
Short fibers are used with cement as binders for the manufacture
of asbestos cement products. After chrysotile the other important
varsities of commercial importance are amosite and crocidolite
both of amphibole group. Amphibole asbestos generally finds
use in heat insulation and treatment of acids. The anthophyllite
and tremolite fibers even through of considerable length are
too weak and brittle to spin. These varieties of amphibole
group are generally used for boiler lagging, hard setting
magnesia composition and as filler, also in asbestos paints
and various asbestos molded articles.
According
to the information available with IBM various classifications
of chrysotile asbestos are follows in India but these are
by and large based on fiber length. This are given below:
| 1.
Grade |
|
As
or A special |
1"
(24.4mm) fibers or larger. |
|
As1 |
1"
(25.4mm) fibers and larger but brittle compared to As
or a special. |
|
A |
¾
to 1" (19.05 to 25.4mm) fibers. |
|
Al |
¾
to 1" (19.05 to 25.4mm) fibers but brittle compared to
A. |
|
A2 |
¾
to 1" (19.05 to 25.4mm) fibers but brittle compared to
Al. |
|
B1 |
¼
" to ¾ (16.35mm to 19.05mm) fibers. |
|
B2 |
¼
to ¾" (6.35 to 19.05mm) fibers but brittle compared to
B1 |
|
C |
Below
¼" fibers (96.25mm) |
2.
Special: |
GradeA |
Above
31.5mm |
Grade |
Between
19 and 31.5 |
GradeB |
Between
6.3 and 19mm |
GradeC |
Between
6.3mm including power |
GradeD |
Dust. |
| 3.
Quebec standard asbestos testing machine classification
of chrysotile asbestos according to groups. |
| Group
No. 1
Group No. 2 |
Crude
Asbestos |
| Milled
Asbestos |
| Standard
Designation of Grades |
Guaranteed
minimum spinning tests. |
| Group
No. 3 (Spinning fibers)
3
D
3
Z |
10.6
– 3.9 – 1.3 – 0.3 – 0 – 8 - 6 – 2 |
Group
No. 4 (Single fibers)
4
D
D
Z |
0 – 7 – 6 - 3
0
– 1.5 – 9.5 - 5 |
Group
No. 5 (Paper fibers)
5
D
5
R |
0 – 0.5 – 5 – 10.5 – 5
0
– 0 – 10 – 6
|
Group
No. 6 (Waste)
6
D |
0 – 0 – 7 – 9 |
Group
No. 7 (Shorts or refuses)
7
D
7
W |
0 - 0 – 5 – 11
0
– 0 – 0 – 16
|
Group
No. 7 (Fleats)
7
FF
7
TF |
No Test
No
Test
|
Group
No. 8 (Sand and gravel)
8
S
8
F |
Less than 50 lb. per ft3 loose measure.
Less
than 75 lb. per ft3 loose measure.
|
Group
No. 9 (Gravel and Stone)
9
T |
More than 75 lb. per ft3 loose measure. |
The
reserves of asbestos have been classified according to the
variety of asbestos i.e., chrysotile, amosite, anthophyllite
and mixed grade in the mineral inventory as on 01.01.1985
and earlier. The exploration agencies have not furnished information
with regard to fiber length, tensile, strength, etc. Although
to some extend the name of the mineral it self reflects its
utility, the required specification for different end use
ought to be kept in view classifying the reserves.
Due
to multifarious uses of asbestos to which it is not a large
number of tests have been evolved by the users as well as
products to evaluate various physical properties to suit their
own requirements. The properties have been mostly specified
for chrysotile asbestos that is most extensively used variety.
The most commonly used fiber length as given under item (I)
above. Grading of other varieties of asbestos is not generally
not done.
It
is suggested that chrysotile asbestos may be classified in
the following three grades depending up on the fiber length
for the purpose of classification of reserves.
|
Grades |
Fiber
Length |
| A |
Fiber
length above 3/4" (19.05mm) |
| B |
Fiber
length above 3/4" (6.35mm) but below 3/4 " (1905mm) |
| C |
Fiber
length below 1/4" (6.35mm) |