Tungsten
Carbide:
Tungsten
carbide is used in cutting tools as well as in wear resisting
material. Apart from industrial cutting tools it is used
as a drill bit in the mining and petroleum industry.
Ferro
– Tungsten:
Earlier
tungsten carbide was used in the defense and tank ammunition
and it has now been replaced by tungsten nickel iron alloy.
Tungsten
Metal / Wires:
High
purity tungsten metal drawn a wire in used as filament in
electrical lamps and as cathodes for electrical tube lamps.
The
other minor areas of used are chemicals, X-ray screens,
television tubes, etc.
The
Chief Tungsten minerals are tungstates of iron, manganese
and calcium, the tungsten ore being wolfram (FeMn) O4
and scheelite, CaWO4.
Tungsten
ore mined are beneficiation to yield desired grade concentrates
which is the starting point for making other down stream
intermediate products like tungsten acid, tungsten mental
powder, ferro-tungsten, tungsten carbide, etc.
The
concentrate specifications for commercial purpose are in
terms of WO3 content. Any concentrates with 65%
and more Wo3 content is considered saleable material.
However, Low-grade concentrates products provided the product
could be obtained at economic costs. As such specification
for the lower grade concentrates can not be prefixed.
Tungsten
Carbide:
The
Specification of the major T. C. tool producers in the country
viz. WIDIA AND SANDVIK along with US specification are given
below:
|
Constituent |
WIDIA%
Wolframite |
SANDIVK
Scheelite
% |
Wolframite |
US
carbide
Scheelite
% |
Wolframite
% |
|
WO3 |
Min.
65 |
Min.
70 |
65 |
65 |
Min.
65 |
|
Sn |
Max.
1.5 |
Max.
2.0 |
0.50 |
0.1 |
Max.
1.5 |
|
As |
Max.
0.25 |
Max.
0.1 |
0.10 |
0.1 |
Max.
0.25 |
|
S |
Max.
0.50 |
Max.
1.0 |
1.00 |
0.50 |
Max.
0.50 |
|
Cu |
Max.
0.05 |
Max.
0.50 |
0.50 |
0.10 |
Max.
0.50 |
|
Sb |
Max.
0.10 |
Max.
1.00 |
-- |
0.10 |
Max.
0.05 |
|
Bi |
Max.
0.20 |
Max.
1.00 |
1.00 |
0.25 |
Max.
0.50 |
|
Mo |
Max.
0.20 |
Max.
0.15 |
-- |
0.10 |
Max.
0.10 |
|
Pb |
Max.
0.05 |
Max.
0.50 |
-- |
0.10 |
Max.
1.00 |
|
Zn |
Max.
0.10 |
-- |
-- |
0.10 |
Max.
1.00 |
|
P |
Max.
0.05 |
Max.
0.05 |
0.05 |
0.05 |
Max.
0.05 |
|
Si |
Max.
2.50 |
Max.
1.50 |
0.50 |
-- |
-- |
|
Ca |
Max.
0.05 |
-- |
0.20 |
-- |
Max.
0.20 |
|
Mn |
No.
Limit |
1.00 |
-- |
2.00 |
(Fe
& Mn) |
|
Fe |
3.00 |
-- |
-- |
-- |
-- |
|
Ca+SiO2 |
-- |
-- |
1.00 |
-- |
-- |
|
F |
-- |
-- |
1.00 |
-- |
-- |
Ferro-tungsten:
The
BIS (IS: 5632 – 1970) has prescribed the following specifications
of concentrates for ferro tungsten industry WO3
65% (min.) P – 0.05% max. As – 01% max., Sn 0.1% max., MnO
– 10 15% max.
Electrical
Industry:
The
industry imports tungsten bars and wires. No specification
is available. The US specification of concentrate for pure
metal making is given below:
WO3
- 65%, Sn – 1.5%, Cu – 0.5%, As – 0.20%, Bi – 0.5%, Sb –
0.5%, Mn – 0.025%, P – 0.50%, S – 0.50%, Pb – 1.0%, Zn –
1.0%, Ca – 0.20%
MDB
suggested the following specifications for wolframite and
scheelite and scheelite concentrate for tungsten carbide
industry.
|
Constituent |
Wolframite
% |
Scheelite
% |
|
WO3 |
Min.
65 |
65
to 70 |
|
Sb |
Max.
1.5 |
Max.
1.5 |
|
P |
Max.
0.05 |
Max.
0.05 |
|
S |
Max.
1.00 |
Max.
1.00 |
|
Cu |
Max.
0.50 |
Max.
0.50 |
|
As |
Max.
0.20 |
Max.
0.10 |
|
Bi |
Max.
1.00 |
Max.
1.00 |
|
Ca |
Max.
0.05 |
-- |
|
Mn |
-- |
1.00 |
|
Fe |
-- |
3.00 |
|
Si |
Max.
1.50 |
Max.
1.50 |
Tungsten
ore as mined is not used directly in the industry as mentioned
above the end use classification of this mineral is not
possible. In the inventory as on 01.01.1985 the following
reserve classification has been followed:
It
was noted that while the resources position of tungsten
in India is much better now as compared to the late 70s,
the grade of most of the deposit is very low. They are mostly
around 0.1% WO3 levels except a few deposits
like Degana Vain Load (0.5% WO3) Kobana 0.3%
WO3 Burugubanda bloom 0.5% WO3. The
working economics of the Indian deposits, therefore, depended
mainly on (I) amenability of the ore to beneficiation and
the beneficiation process and (ii) the quantity and number
of co-products and by-products that could be obtained while
mining and processing such deposits. While in the gold mines,
tungsten is a by-product, in Burungubanda it occurs with
graphite, in salda with fluorite and in kobana no-Ta may
be available in the top laterite. In the granite in Deana
the WO3 is only around 0.04% to 0.2%. However,
it may be an economic preposition if the indicated lithium
levels are confirmed and recovery of associated tin is also
possible.
The
following grade-wise classification of reserves and resources
may be of use.
Reserves
- WO3 0.30% and above average.