Chromite
is consumed in metallurgical, refractory and chemical industries.
By far, the metallurgical industries are the main consumers
of chromite followed by refractories and chemicals. It is
used in the manufacture of high carbon and low carbon ferro-chrome
as also charge-chrome. In combination with magnetite in varying
proportion, it is used to manufacture refractory bricks. In
chemical industries, it is used for the manufacture of sodium
chromate and dichromate. Other chromium chemicals are derived
from these compounds, which find a number of uses in the industry.
1.
Metallurgical Use:
In
the manufacturer of high carbon and low carbon ferrochormite,
by and large, high-grade chromite is used. However, lower
grade chrome is required for the manufacture of charge chrome.
There is no BIS specification for metallurgical grade chromite.
The user industries prefer the following grades:
| (a) |
Ferro
Chrome: |
| i |
Cr2O3
|
46%
(min.) |
| ii |
SiO2
|
2
- 6% |
| iii |
A12O3
|
3
- 10% |
| iv |
Cr
: Fe |
2.6
: 1 (min.) |
| v |
S |
0.5%
(max.) |
| vi |
P |
0.2%
(max.) |
| vii |
Physical
Characteristics |
Lump
25 mm to 150 mm |
| viii |
Fines
up to 10 mm are also used. |
|
| (b) |
Charge
Chrome: |
| i |
Cr2O3
|
40%
(min.) |
| Ii |
Cr
: Fe |
1
: 6 (min.) |
2.
Refractory Use:
There
is no BIS specification for refractory grade chromite. The
sub-committee on refractory raw material of the DGTD in their
report dated August 1985, has examined the specification of
chromite for refractory industries, and has specified the
following 4 grades:
| Special
grade
|
Grade
I |
Grade
II |
Grade
III |
| Cr2O3
52 – 54% |
52
– 54% |
46
– 48 % |
40
– 42% |
| SiO2
2% (max.) |
5%
(max.) |
6
- 9 % |
9
– 12% |
| CaO
1% (max.) |
1%
(max.) |
1%
(max.) |
1%
(max.) |
| FeO
20% (max.) |
20%
(max.) |
20%
(max.) |
20%
(max.) |
The
ore should be lumpy in nature and on crushing through a hammer
type of impact mill, not more than 30% of less than one-millimeter
size should be generated.
| On
Dry Basis: |
| i |
Cr2O3
|
44%
(min.) |
| ii |
FeO |
20%
(max.) |
| iii |
A12O3
|
3%
(max.) |
| Iv |
SiO2
|
7%
(max.) |
| V |
CaO |
3%
(max.) |
| Vi |
MgO |
14%
(max.) |
3.
Chromite as used in foundry:
The
BIS (IS: 6788 – 1973) has prescribed the following specification
on dry mass basis. The loss on ignition shall be 1% (max.).
| |
Constituent
|
Requirement |
| I |
Cr2O3 |
44%
(min.) |
| Ii |
FeO |
20%
(max.) |
| Iii |
SiO2 |
7%
(max.) |
| Iv |
CaO |
3%
(max.) |
Future
Trends:
It
is seen that the specifications for the metallurgical use
are becoming less rigid. For the manufacturer a ferro chrome
in the requirement Cr2O3 has reduced
from 48% to 46% (min.) and Cr: Fe ration from 2.8:1 to 2.
6:1.The specification of ores for charge chrome industries
is far more rigid. This has resulted in broadening the base
of supplies of metallurgical grade ore.
Similar
relaxation in the specification is also noticed for the refractory
industry. R & D efforts are a foot to utilize chromite
fines in the manufacture of refractory. The Mineral Development
Board has taken initiative to initiate research to utilize
fines for the manufacture of mag-chrome sinters. These trends
indicate that chromite fines may be used in the manufacture
of refractory and in that event the shortages experienced
in the supply of chromite lumps for refractory industry will
not be there.
The
situation with regard to end-use classification of chromite
reserves appears to be satisfactory. The Geological survey
of India, the directorate of Geology & Mining. Orissa,
The Orissa Mining Corporation and the Mineral Exploration
Corporation Ltd., Have conducted exploration in the most important
chromite hearing areas of Orissa and have categorized reserve
as given below: